CHEM 110 2006

Syllabus

Assigned problems are in orange.

Chapter 12 problems:

 7,9,13,15,19,20,21,23,24c,d,27,49b,53,63,69,89,92,98

Answers:

#20      a. – same

            b. – same

            c. – structural isomers

            d. – unrelated

#24      c. 2,4-dimethylhexane

            d. 2,3-dimethylhexane

Chapter 13 problems:

 1(classify as saturated or unsaturated only) 7a,b,e,11a,e, 19a,b,21b,c,31,33,35,45a,b,c,51,53,55.59a,c,67,69a,c,d,77,78,82

Chapter 14 problems:

1,7,11a-d,29,37,43,51c,55,56,57a,b,69a-d, 83,87,107,108,109,111

Answer to 56: The second is not a phenol because the OH must be attached to a benzene ring - a hexagon with a circle inside.

Answer to 108: c - it should be isopropyl alcohol

Extra questions: What are the organic products, if any, obtained from treating each alcohol in question 14.8 a,d and e with K2Cr2O7 and H2SO4?

Answers:

Chapter 15 problems:

5a-e,7,9,11a-c,f,15a-c,21a-d,27a,b,d,29b,45b,d,e,51,54,55,87

Answer: 54 – Ag+

Chapter 16 problems

1a,b,c,e,3a-c,7a,b,33a-c,39,43a,45a,49,49a-c,55a-d,

81b,d,106a,c

Stop for Test #1

For Second Test:

Assigned problems are in red.

Chapter 17 problems:

1,3,5,7a,b,c,e,f,29,37a,b,d,39a,c,d,43,46(structure only),59a,c,d,f,60a,f,61,79b,83a,d,90a,b,94,101,102

# 46

#60 a - true, f - true

(answers to #94 and 102 are in the back of the book)

"Extra Problems - do all

Chapter 18 problems:

17,19,33,35a,b,c,37,39,43a,53,57,59,67a,b,71,87a,c,93,95,97,98a,b,109 (skip chitin),111,122,129,130

ANSWERS: 98a - reducing; 98b - nonreducing

Do all of the "Study  Questions" on the handout except questions 2,4 and 5.

On the "Study Outline" for test #2, skip "Know what high-fructose corn syrup is and how it is made."

Assigned problems are in green.

For test #3:

Chapter 19 problems

1,3,9,13,17,19a,b,c,23,27 (palmitic acid is 16:0),35a,b,d,37,43b,49,53,55,59,69,77,83,87,103,110,111,117a,b,c,118(skip b),124,129

Answer 110 - aspirin blocks the conversion of arachidonic acid to a prostaglandin, the molecule which causes inflammation

Answer 118 a - energy-storage, c - membrane, d - messenger, e - membrane, f - messenger

 

Handout: "Study Questions" for lipids

Do all questions except #4

Chapter 20 problems:

3,15 (given structures),16 (given structures), 17,18,23d,35,37,38,41,47,63,64,66,69,72,75,76,78,79,81,83,

90,91,101,111,113,116,117,119,120

Do all of the "Study questions on Proteins"

Problems Chapter 21:

1,3,21,25,39,41,45,53,55,57,105

There are no extra study questions for enzymes.

 

 

Assigned problems are in black

Study Questions on Metabolism :

Do ALL problems

 

Chapter 23 problems:

 5,19,23,35,49,51a,b,52,a,b,c,65,81,91,93,104

Answer 52 a - 3    b - 1    c - 2

 

Chapter 24 problems:

                  Glycolysis – 9,17,18,23,31a,38,43

Answer for 18: 2 each

                 38: see p. 752 (top)

                  Glycogen – 51

                  Gluconeogenesis and hormonal control – 71,81,82

                    Answer 82 - lowers blood glucose through processes given in class

                  General – 96a,b,c

 

Chapter 25 problems:

        Fat catabolism – 25,37,43a-d,45,49,51,61

        Fat  biosynthesis – 63,74

    105,106

Answer 74: Because they are made from the two carbon acetyl group of Acetyl CoA

Chapter 26 problems:

17,31,35c,41,58,65

Answer 58: carbon dioxide and ammonia

93,94

 

Question for the TEST on Nucleic Acids:

Chapter 22: 1,5,9,11b,c,d,15,25,29,35,37,

51b-d,53,57,63,71,66,85,128,129,130

Do all the questions on "Study questions on Nucleic Acids" except for numbers 14 and 18.